
The narrow band sensors was designed to achieve a stoichiometric (14.7:1) mixture under closed loop conditions, as
this is the point where optimum catalytic converter efficiency is achieved.
There are ways to guess your actual air/fuel ratio (AFR), but there is only
one tool which can give you exact values. That tool is the wide band oxygen
sensor. The wide-band sensor expands on the principle of the two-state sensor
narrow band function by incorporating a second chamber, the pump cell. The
Wide Band Sensors are used in the pre catalyst position in the exhaust stream.
They look similar to the Oxygen sensors that you have been accustomed to,
however there are some differences.
The criteria for checking the feedback of these sensors was how far it strayed from the stoichiometric voltage of 450 millivolts. Anything above that voltage, meant a rich mixture and called for the ECM to lean things out by reducing injector "on time". Conversely, if the voltage was lower than 450mv, there would be an increase in injector "on time".
Although somewhat accurate, these sensors are only capable of telling us that we are out of the ideal 14.7:1. A two state sensor, meaning we are lean or rich and that's it. The sensor is also sampled approximately every 50 milliseconds (ms), so there is a lag time between checks of the sensor which can lead to gaps and inaccurate readings and corrections to the A\F ratio.
The sensors for wide band systems are very similar to the ones that you are used to. They look a lot alike with a few exceptions. The sensors will have 6 wires connected to them (Heater power and ground, Reference high and low, and 2 wires for pumping current. The ECM is attempting to maintain a constant 450 mV potential difference between the reference voltage and low reference circuits by increasing or decreasing the abundance of oxygen ions in the exhaust gas sample chamber, an external electrical force is required to move the oxygen ions. That's where the 2 extra wires for the pump current comes in. The ECM relies on Pumping Current to move electrons, here's how;
The ECM supplies a pumping voltage to the ion conductive material
that separates the exhaust gas sample chamber and the exhaust stream. As the
pumping voltage, and thus the pumping current, increases or decreases, as well
as changes polarity, oxygen ions will be moved from the exhaust stream through
the ion conductive material into the exhaust gas sample chamber. Ions may also
be moved from the exhaust gas sample chamber through the ion conductive material
back into the exhaust stream.

The ECM used to keep an eye on the 450mv
as stated above, now the pumping current, polarity and reference voltage are
watched. A value greater than 1.000 indicates a lean air/fuel ration;
conversely a value less than 1.000 indicates a rich air/fuel ratio. At idle the lambda value will typically fluctuate between .900 and
1.000. The advantage to this is the fact that the pumping current can be
monitored constantly for better AFR control whereas before we had the lag time
between samples. Trends in the AFR can be monitored closer than ever giving us
cleaner air and better mileage.
So to put in a thumbnail sketch, the wide band O2 sensor is a
conventional switching sensor combined with an oxygen pump. Oxygen is pumped
into or out of the exhaust sample chamber in order to produce it's 450mv. The
amount of oxygen required to achieve this is proportional to the oxygen content
of the sample.
Mik Stubing - Lead Instructor GMTCNY